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Application of spectral technology in flame measurement

Jiaxun LIU, Xiaoshu CAI, Zenghao ZHU, Huinan YANG

《能源前沿(英文)》 2014年 第8卷 第1期   页码 138-143 doi: 10.1007/s11708-013-0283-5

摘要: Spectral technology has become an important detection method due to its advantages such as non-intrusive measurement and on-line analysis. In this paper, two applications of spectral technology in thermal detection were proposed. First, a novel spectroscopic method based on Planck’s law for measurement of emissivity was introduced. The emissivity, obtained by comparing the radiation intensity of the blackbody which had the same temperature as the flame with the detected intensity of the flames, could be used for on-line measurements and had a relatively higher upper temperature limit. Then, a spectroscopic method for composition detection of blended fuels was proposed based on the emissivity measured. By comparing the spectra of blended fuels and single fuels, the ratio of single fuels of the blended fuel could be calculated. The measurement system proposed in this paper, which consists of a spectrometer and a computer, is very compact.

关键词: spectrum     emissivity measurement     component of fuel     near-infrared spectrometer    

Modeling of oil near-infrared spectroscopy based on similarity and transfer learning algorithm

Yifei Wang, Kai Wang, Zhao Zhou, Wenli Du

《化学科学与工程前沿(英文)》 2019年 第13卷 第3期   页码 599-607 doi: 10.1007/s11705-019-1807-2

摘要: Near-infrared spectroscopy mainly reflects the frequency-doubled and total-frequency absorption information of hydrogen-containing groups (O‒H, C‒H, N‒H, S‒H) in organic molecules for near-infrared lights with different wavelengths, so it is applicable to testing of most raw materials and products in the field of petrochemicals. However, the modeling process needs to collect a large number of laboratory analysis data. There are many oil sources in China, and oil properties change frequently. Modeling of each raw material is not only unfeasible but also will affect its engineering application efficiency. In order to achieve rapid modeling of near-infrared spectroscopy and based on historical data of different crude oils under different detection conditions, this paper discusses about the feasibility of the application of transfer learning algorithm and makes it possible that transfer learning can assist in rapid modeling using certain historical data under similar distributions under a small quantity of new data. In consideration of the requirement of transfer learning for certain similarity of different datasets, a transfer learning method based on local similarity feature selection is proposed. The simulation verification of spectral data of 13 crude oils measured by three different probe detection methods is performed. The effectiveness and application scope of the transfer modeling method under different similarity conditions are analyzed.

关键词: near-infrared spectroscopy     transfer learning     similarity     modeling    

Near-infrared benzodiazoles as small molecule environmentally-sensitive fluorophores

《化学科学与工程前沿(英文)》 2022年 第16卷 第1期   页码 128-135 doi: 10.1007/s11705-021-2080-8

摘要: The development of fluorophores emitting in the near-infrared spectral window has gained increased attention given their suitable features for biological imaging. In this work, we have optimised a general and straightforward synthetic approach to prepare a small library of near-infrared-emitting C-bridged nitrobenzodiazoles using commercial precursors. C-bridged benzodiazoles have low molecular weight and neutral character as important features that are not common in most near-infrared dyes. We have investigated their fluorescence response in the presence of a wide array of 60 different biomolecules and identified compound 3i as a potential chemosensor to discriminate between Fe2+ and Fe3+ ions in aqueous media.

关键词: fluorescence     probes     iron     screening     library    

Near-infrared fluorescent probe for fast track of cyclooxygenase-2 in Golgi apparatus in cancer cells

Bhaskar Gurram, Miao Li, Jiangli Fan, Jingyun Wang, Xiaojun Peng

《化学科学与工程前沿(英文)》 2020年 第14卷 第1期   页码 41-52 doi: 10.1007/s11705-019-1796-1

摘要: Cyclooxygenase-2 (COX-2) has been used as an excellent traceable biomarker, and exists maximally in Golgi apparatus (Cancer cells). Celecoxib (CCB) is a selective inhibitor for COX-2, and has been used as one of non-steroidal anti-inflammatory drug. Herein we report the conjugation of nile blue (NB) with CCB via a six-carbon linkage to form a fluorescence probe NB-C6-CCB for the detection of COX-2. NB-C6-CCB displays strong fluorescence with the emission peak centered at near-infrared wavelength (700 nm) in tumor cells or tumor tissues with high expression of COX-2. Importantly, NB-C6-CCB can discriminate cancer cells (MCF-7) fluorescence intensity from normal ones (COS-7) in the co-culture medium under confocal microscope. Subcellular localization of the NB-C6-CCB preferentially points to the Golgi apparatus and increases the fluorescent intensity. The competitive analysis (with CCB) and Native-PAGE analysis confirmed that NB-C6-CCB shows selective binding affinity towards COX-2 enzyme. Competitive analysis with CCB (flow cytometry assay) revealed the fluorescence intensity fluctuation due to pretreatment of CCB with different concentrations, indicating that the NB-C6-CCB is a precise or sensitive probe for the COX-2. Tumor tissue (depth: 500 µm), organs and mice imaging tests show excellent near-infrared visualization, specific localization and identification of tumors.

关键词: cyclooxygenase-2     nile blue     CCB     Golgi apparatus     NIR imaging    

Factors influencing near infrared spectroscopy analysis of agro-products: a review

Xiao XU, Lijuan XIE, Yibin YING

《农业科学与工程前沿(英文)》 2019年 第6卷 第2期   页码 105-115 doi: 10.15302/J-FASE-2019255

摘要:

The near infrared (NIR) spectroscopy technique has wide applications in agriculture with the advantages of being nondestructive, sensitive, safe and rapid. However, there are still more than 40 error sources influencing the robustness and accuracy of its calibration and operation. Environmental, sample and instrument factors that influence the analysis are discussed in this review, including temperature, humidity and other factors that introduce uncertainty. Error sources from livestock products, fruit and vegetables, which are the most common objects in the field of NIR analysis, are also emphasized in the second part. In addition, studies utilizing different instruments, spectral pretreatments, variable selection methods, wavelength ranges, detection modes and calibration methods are tabulated to illustrate the complications they introduce and how they influence NIR analysis. It is suggested that large scale of data with abundant varieties can be used to build a more robust calibration model, in order to improve the robustness and accuracy of the NIR analytical model, and overcome problems caused by confining analysis to too many uniform samples.

关键词: agro-product     error source     influence factor     near infrared spectroscopy    

光纤微针装置中增强对流药物输注的热强化表征 Article

R. Lyle Hood,Rudy T. Andriani,Tobias E. Ecker,John L. Robertson,Christopher G. Rylander

《工程(英文)》 2015年 第1卷 第3期   页码 344-350 doi: 10.15302/J-ENG-2015077

摘要:

增强对流输注 (CED) 是一项颇具前景的技术,其借助压力驱动流来增强输注药物进入细胞间隙的穿透力。为进一步提升CED的药物分布容积,笔者发明了一种可产生局部亚致死热量的光纤微针装置。本文试图在琼脂糖组织模型中对该技术进行定量表征。在15 °C、20 °C、25 °C和30 °C的恒温条件下,染料的输注在质量分数为0.6%的琼脂糖组织模型中进行分析。输注指标通过自定义阴影成像技术和图像处理算法进行定量。利用所获数据构建一个分布容积的经验预测时序模型作为组织模型温度的函数。接下来通过一组概念验证实验来评估液体输注时新型光纤装置产生局部光加热的能力。恒温输注显示温度和分布容积呈正相关,在100 min时,在30 °C恒温条件下体积扩散是在15 °C恒温条件下的7倍。在光加热 (1064 nm,500 mW) 过程中,输注呈现相似的效果:与对照组 (0 mW) 相比,输注体积在4 h时增大了3.5倍。本文的分析和结果为体积扩散的热介导增强提供了特征描述及新思路。

关键词: 近红外激光     热化学疗法     琼脂糖     光加热     微导管     恶性胶质瘤    

Review on the applications of Tropospheric Emissions Spectrometer to air-quality research: Perspectives

Yuxuan WANG, Yuqiang ZHANG, Jiming HAO,

《环境科学与工程前沿(英文)》 2010年 第4卷 第1期   页码 12-19 doi: 10.1007/s11783-010-0012-9

摘要: The Tropospheric Emissions Spectrometer (TES) aboard the National Aeronautics and Space Administration’s (NASA’s) Aura satellite launched in July 2004 is the first satellite instrument to provide simultaneous retrievals of ozone (O) and carbon monoxide (CO) throughout the Earth’s lower atmosphere. This paper briefly reviews the TES instrument, the retrieval of O and CO profiles, and the validation of the retrievals. The applications of TES O and CO products include mapping the vertical and horizontal distribution of tropospheric O and CO and their correlations, examining the regional and continental outflow, and analyzing the variability of the two species associated with certain weather and climatic conditions, such as El Niño and the Asian monsoon. TES retrievals of O and CO offer an important new source of satellite data over China with good spatial and temporal coverage that can provide evaluation and constraints on the performance of chemical transport models in simulating the general features of ozone pollution over China. Special observations have been conducted and requests may be submitted to the TES team to make geographically focused observations of O and CO over China.

关键词: Tropospheric Emissions Spectrometer (TES)     ozone     carbon monoxide     China    

Air bearing center cross gap of neutron stress spectrometer sample table support system

Yang LI,Yunxin WU,Hai GONG,Xiaolei FENG

《机械工程前沿(英文)》 2016年 第11卷 第4期   页码 403-411 doi: 10.1007/s11465-016-0405-y

摘要:

A support system is the main load-bearing component of sample table for neutron stress spectrometer, and air bearing is an important element of a support system. The neutron stress spectrometer sample table was introduced, and the scheme for air bearing combination was selected. To study the performance of air bearing center cross gap, finite element models (FEMs) were established based on air motion and Reynolds equations, effects of air supply pressure, and gap parameters on the overturning moment and bearing capacity of air bearing center cross gap were analyzed. Results indicate that the width, depth, and height differences of the marble floor gap played important roles in the performance of the air bearing. When gap width is lesser than 1 mm and gap depth is lower than 0.4 mm, bearing capacity and overturning moment would vary rapidly with the variation of the width and depth. A gap height difference results in the bearing capacity dropping rapidly. The FEM results agree well with experimental results. Further, findings of the study could guide the design of the support system and marble floor.

关键词: neutron stress spectrometer     sample table     support system     air bearing     center cross gap     simulation     experiment    

A building unit decomposition model for energy leakage by infrared thermography image analysis

Yan SU, Fangjun HONG, Lianjie SHU

《能源前沿(英文)》 2020年 第14卷 第4期   页码 901-921 doi: 10.1007/s11708-020-0679-y

摘要: A quantitative energy leakage model was developed based on the thermography image data measured for both external and internal building surfaces. The infrared thermography images of both surfaces of doors, windows, and walls of an office building in the Hengqin Campus of University of Macao were taken at various times in a day for four seasons. The transient heat flux for sample units were obtained based on measurements of the seasonal transient local temperature differences and calculations of the effective thermal conductivity from the multiple-layer porous medium conduction model. Effects of construction unit types, orientations, and seasons were quantitatively investigated with unit transient orientation index factors. The corresponding electric energy consumption was calculated based on the air conditioning system coefficient of performance of heat pump and refrigerator cycles for different seasons. The model was validated by comparing to the electric meter records of energy consumption of the air conditioning system. The uncertainties of the predicted total building energy leakage are about 14.7%, 12.8%, 12.4%, and 15.8% for the four seasons, respectively. The differences between the predicted electric consumption and meter values are less than 13.4% and 5.4% for summer and winter, respectively. The typical daily thermal energy leakage value in winter is the highest among the four seasons. However, the daily electric energy consumption by the air conditioning system in summer and autumn is higher than that in winter. The present decomposition model for energy leakage is expected to provide a practical tool for quantitative analysis of energy leakage of buildings.

关键词: heat conductivity     heat coefficient     heat &fllig     ux     infrared thermography     thermal image    

A spectrometer for measuring particle size distributions in the range of 3 nm to 10 μm

Jieqiong LIU,Jingkun JIANG,Qiang ZHANG,Jianguo DENG,Jiming HAO

《环境科学与工程前沿(英文)》 2016年 第10卷 第1期   页码 63-72 doi: 10.1007/s11783-014-0754-x

摘要: A spectrometer combining electrical mobility sizing and aerodynamic sizing was developed to measure aerosol size distributions in the range of 3 nm to 10 μm. It includes three instruments which cover different size ranges (a nano scanning mobility particle sizer (NSMPS, 3 – 60 nm), a regular scanning mobility particle sizer (RSMPS, 40 – 700 nm), and an aerodynamic particle sizer (APS, 550 nm – 10 μm)). High voltage and sheath flow of the NSMPS and RSMPS were supplied using two home-built control boxes. A LabVIEW program was developed for spectrometer automatic operation. A linear inversion method was applied to correct particle multiple charging effects and to integrate data from the three instruments into a wide-range size distribution. Experiments were conducted to compare distributions in the overlap size ranges measured by three instruments. Good agreement between the NSMPS and RSMPS was achieved after correcting for the difference in counting efficiencies of the two particle counters. Aerodynamic size distributions reported by the APS were converted to mobility size distributions by applying an effective density method. Distributions measured by the RSMPS and APS were consistent in the overlap size range of 550 – 700 nm. A full spectrum in the size range of 3 nm to 10 μm was demonstrated by measuring aerosol generated using a mixture of different sized polystyrene latex spheres.

关键词: spectrometer     particle size distribution     electrical mobility     linear inversion     aerodynamic diameter    

Spontaneous firing properties of rat medial vestibular nucleus neurons in brain slices by infrared visual

XIA Jiao, KONG Weijia, ZHU Yun, ZHOU Yan, ZHANG Yu, GUO Changkai

《医学前沿(英文)》 2008年 第2卷 第3期   页码 264-268 doi: 10.1007/s11684-008-0050-x

摘要: Domestic application of infrared patch clamp techniques on brain slices is limited. The key of the technique is to prepare high-quality brain slices. The present paper describes the preparation procedure of brainstem slices and the spontaneous firing properties of rat medial vestibular nucleus (MVN) neurons. By infrared differential interference contrast technique, neurons of rat MVN were visualized directly at the depth of 50–100 ?m underneath the surface of slices. Firing activities of MVN neurons were recorded by the whole-cell patch clamp technique in artificial cerebrospinal fluid (ACSF) and low Ca - high Mg fluid. The firing mode was more irregular and depressive in low Ca - high Mg fluid than in ACSF. According to the averaged waveform of action potentials, cells were classified as the neurons with monophasic after-hyperpolarization potential (AHP), and the neurons with biphasic AHP. The resting membrane potential (RMP), input resistance (Rin) and membrane capacitance (Cm) of neurons were recorded and compared between groups. With infrared videomicroscopy, patch clamp recordings could be made under direct observation in freshly prepared brainstem slices. The discharge activities of MVN neurons were spontaneous and the firing mode was modulated by extracellular calcium concentration. The basic membrane properties of two types of neurons were not significantly different, while the differences in waveform might play a role in the segregation between tonic and kinetic cells.

关键词: resistance     infrared     infrared videomicroscopy     depressive     after-hyperpolarization potential    

Study on the Path of “Near-zero Emission” Coal-based Clean Energy Ecosystem Development

Zhang Yu-zhuo

《工程管理前沿(英文)》 2014年 第1卷 第1期   页码 37-41 doi: 10.15302/J-FEM-2014007

摘要: Developing a "near-zero emission" coal-based clean energy ecosystem bears great significance for the sustainable development of clean energy in China and the world at large. This article delves into the development strategy, implementation pathways and key priorities of China's "near-zero emission" coal-based clean energy ecosystem, and in turn proposes specific measures to underpin the development and implementation of such system.

关键词: near-zero emission     clean energy ecosystem     study on the path    

Research and industrialization of near-net rolling technology used in shaft parts

Zhenghuan HU, Baoyu WANG, Zhenhua ZHENG

《机械工程前沿(英文)》 2018年 第13卷 第1期   页码 17-24 doi: 10.1007/s11465-018-0480-3

摘要:

Shaft part rolling is an efficient and green near-net shaping technology offering many advantages, including high production efficiency, high material utilization rate, high product quality, and excellent production environment. In this paper, the features of shaft part rolling are introduced along with the working principles of two main shaft part rolling technologies, namely, cross wedge rolling (CWR) and skew rolling (SR). In relation to this technology, some R&D achievements gained by the University of Science and Technology Beijing are summarized. Finally, the latest developments in shaft part rolling are presented, including SR steel balls, precise forming of camshaft blank by CWR, SR phosphorous copper balls at room temperature, and CWR hollow axle sleeve. Although the shaft part rolling technology has been widely used in China, it only accounts for about 15% of applicable parts at present. Nevertheless, this technology has broad application prospects.

关键词: cross wedge rolling     skew rolling     near-net rolling     shaft part    

MEMS-based thermoelectric infrared sensors: A review

Dehui XU, Yuelin WANG, Bin XIONG, Tie LI

《机械工程前沿(英文)》 2017年 第12卷 第4期   页码 557-566 doi: 10.1007/s11465-017-0441-2

摘要:

In the past decade, micro-electromechanical systems (MEMS)-based thermoelectric infrared (IR) sensors have received considerable attention because of the advances in micromachining technology. This paper presents a review of MEMS-based thermoelectric IR sensors. The first part describes the physics of the device and discusses the figures of merit. The second part discusses the sensing materials, thermal isolation microstructures, absorber designs, and packaging methods for these sensors and provides examples. Moreover, the status of sensor implementation technology is examined from a historical perspective by presenting findings from the early years to the most recent findings.

关键词: thermoelectric infrared sensor     CMOS-MEMS     thermopile     micromachining     wafer-level package    

Identify the contribution of vehicle non-exhaust emissions: a single particle aerosol mass spectrometer

《环境科学与工程前沿(英文)》 2023年 第17卷 第5期 doi: 10.1007/s11783-023-1662-8

摘要:

● A single particle observation was conducted in a high traffic flow road environment.

关键词: Non-exhaust emissions     SPAMS     PMF     Roadside environment    

标题 作者 时间 类型 操作

Application of spectral technology in flame measurement

Jiaxun LIU, Xiaoshu CAI, Zenghao ZHU, Huinan YANG

期刊论文

Modeling of oil near-infrared spectroscopy based on similarity and transfer learning algorithm

Yifei Wang, Kai Wang, Zhao Zhou, Wenli Du

期刊论文

Near-infrared benzodiazoles as small molecule environmentally-sensitive fluorophores

期刊论文

Near-infrared fluorescent probe for fast track of cyclooxygenase-2 in Golgi apparatus in cancer cells

Bhaskar Gurram, Miao Li, Jiangli Fan, Jingyun Wang, Xiaojun Peng

期刊论文

Factors influencing near infrared spectroscopy analysis of agro-products: a review

Xiao XU, Lijuan XIE, Yibin YING

期刊论文

光纤微针装置中增强对流药物输注的热强化表征

R. Lyle Hood,Rudy T. Andriani,Tobias E. Ecker,John L. Robertson,Christopher G. Rylander

期刊论文

Review on the applications of Tropospheric Emissions Spectrometer to air-quality research: Perspectives

Yuxuan WANG, Yuqiang ZHANG, Jiming HAO,

期刊论文

Air bearing center cross gap of neutron stress spectrometer sample table support system

Yang LI,Yunxin WU,Hai GONG,Xiaolei FENG

期刊论文

A building unit decomposition model for energy leakage by infrared thermography image analysis

Yan SU, Fangjun HONG, Lianjie SHU

期刊论文

A spectrometer for measuring particle size distributions in the range of 3 nm to 10 μm

Jieqiong LIU,Jingkun JIANG,Qiang ZHANG,Jianguo DENG,Jiming HAO

期刊论文

Spontaneous firing properties of rat medial vestibular nucleus neurons in brain slices by infrared visual

XIA Jiao, KONG Weijia, ZHU Yun, ZHOU Yan, ZHANG Yu, GUO Changkai

期刊论文

Study on the Path of “Near-zero Emission” Coal-based Clean Energy Ecosystem Development

Zhang Yu-zhuo

期刊论文

Research and industrialization of near-net rolling technology used in shaft parts

Zhenghuan HU, Baoyu WANG, Zhenhua ZHENG

期刊论文

MEMS-based thermoelectric infrared sensors: A review

Dehui XU, Yuelin WANG, Bin XIONG, Tie LI

期刊论文

Identify the contribution of vehicle non-exhaust emissions: a single particle aerosol mass spectrometer

期刊论文